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Synthesis of a 1-aza-2-phospha-acenaphthene complex profiting from coordination enabled chloromethane elimination

Despite debate on intramolecular N→P interactions in peri-substituted naphthalene derivatives their coordination chemistry has not yet been reported. Herein, we describe bonding in and reactivity of dichloro(8-dimethylamino-1-naphthyl)phosphane towards pentacarbonyltungsten(0) reagents. A 1-aza-2-ph...

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Detalles Bibliográficos
Autores principales: Biskup, David, Bergmann, Tom, Schnakenburg, Gregor, Gomila, Rosa M., Frontera, Antonio, Streubel, Rainer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10346357/
https://www.ncbi.nlm.nih.gov/pubmed/37456542
http://dx.doi.org/10.1039/d3ra04352e