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A Pd-catalyzed highly selective three-component protocol for trisubstituted allenes

Herein we report the first example of a Pd-catalyzed highly selective three-component reaction of alkynyl-1,4-diol dicarbonates, organoboronic acids, and malonate anions for the efficient synthesis of trisubstituted 2,3-allenyl malonates not readily available by the known protocols. The reaction dem...

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Detalles Bibliográficos
Autores principales: Li, Can, Zhou, Zhengnan, Ma, Shengming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10355113/
https://www.ncbi.nlm.nih.gov/pubmed/37476716
http://dx.doi.org/10.1039/d3sc01849k