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The influence of fluorination on the dynamics of the F(−) + CH(3)CH(2)I reaction

The competition between the bimolecular nucleophilic substitution (S(N)2) and base-induced elimination (E2) reaction and their intrinsic reactivity is of key interest in organic chemistry. To investigate the effect of suppressing the E2 pathway on S(N)2 reactivity, we compared the reactions F(−) + C...

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Detalles Bibliográficos
Autores principales: Gstir, Thomas, Michaelsen, Tim, Long, Bryan A., Nacsa, András B., Ayasli, Atilay, Swaraj, Dasarath, Zappa, Fabio, Trummer, Florian, Ard, Shaun G., Shuman, Nicholas S., Czakó, Gábor, Viggiano, Albert A., Wester, Roland
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10355169/
https://www.ncbi.nlm.nih.gov/pubmed/37409391
http://dx.doi.org/10.1039/d3cp02110f