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Ru(phen)(3)Cl(2)‐Catalyzed Chlorotrifluoromethylation of Unactivated Alkenes

A novel Ru(phen)(3)Cl(2)‐catalyzed free‐radical chlorotrifluoromethylation reaction of unactivated olefins was investigated. Substituted 8‐aminoquinoline‐derived inert enamides were reacted with the Togni regent to afford a broad range of Cl‐containing trifluoromethyl derivatives in good yields. The...

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Detalles Bibliográficos
Autores principales: Su, Wenhao, Cui, Jing, Zeng, Runsheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10362121/
https://www.ncbi.nlm.nih.gov/pubmed/37480185
http://dx.doi.org/10.1002/open.202300068