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Construction of C-B axial chirality via dynamic kinetic asymmetric cross-coupling mediated by tetracoordinate boron

Catalytic dynamic kinetic asymmetric transformation (DyKAT) provides a powerful tool to access chiral stereoisomers from racemic substrates. Such transformation has been widely employed on the construction of central chirality, however, the application in axial chirality remains underexplored becaus...

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Detalles Bibliográficos
Autores principales: Yang, Kai, Mao, Yanfei, Zhang, Zhihan, Xu, Jie, Wang, Hao, He, Yong, Yu, Peiyuan, Song, Qiuling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10366327/
https://www.ncbi.nlm.nih.gov/pubmed/37488114
http://dx.doi.org/10.1038/s41467-023-40164-6