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Stereospecific Cu(I)-Catalyzed C–O Cross-Coupling Synthesis of Acyclic 1,2-Di- and Trisubstituted Vinylic Ethers from Alcohols and Vinylic Halides

[Image: see text] CuI and trans-N,N′-dimethylcyclohexyldiamine catalyze the single-step C–O bond cross-coupling between 1,2-di- and trisubstituted vinylic halides with functionalized alcohols, producing acyclic vinylic ethers. This stereospecific transformation selectively gives each of the (E)- and...

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Detalles Bibliográficos
Autores principales: Pham, San L., Kim, Taehee, McDonald, Frank E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10367064/
https://www.ncbi.nlm.nih.gov/pubmed/37437300
http://dx.doi.org/10.1021/acs.orglett.3c01849