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Toward Kilogram-Scale Peroxygenase-Catalyzed Oxyfunctionalization of Cyclohexane

[Image: see text] Mol-scale oxyfunctionalization of cyclohexane to cyclohexanol/cyclohexanone (KA-oil) using an unspecific peroxygenase is reported. Using AaeUPO from Agrocybe aegerita and simple H(2)O(2) as an oxidant, cyclohexanol concentrations of more than 300 mM (>60% yield) at attractive pr...

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Detalles Bibliográficos
Autores principales: Hilberath, Thomas, van Oosten, Remco, Victoria, Juliet, Brasselet, Hugo, Alcalde, Miguel, Woodley, John M., Hollmann, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10367066/
https://www.ncbi.nlm.nih.gov/pubmed/37496955
http://dx.doi.org/10.1021/acs.oprd.3c00135