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Synthesis of Highly Functionalized Bismacycles via Post-Transmetallation Modification of Arylboronic Acids

[Image: see text] Bismacycles featuring a sulfone-bridged scaffold have recently been developed as versatile and convenient electrophilic arylating agents. Here, we report that the exocyclic aryl group, which is ultimately transferred to a nucleophilic coupling partner, can be functionalized through...

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Detalles Bibliográficos
Autores principales: Sivanandan, Sudheesh T., Owen, Benjamin, Guiry, Patrick J., Ball, Liam T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10367077/
https://www.ncbi.nlm.nih.gov/pubmed/37436366
http://dx.doi.org/10.1021/acs.joc.3c00361