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Rational Design of Persistent Phosphorus-Centered Singlet Tetraradicals and Their Use in Small-Molecule Activation

[Image: see text] Biradicals are important intermediates in the process of bond formation and breaking. While main-group-element-centered biradicals have been thoroughly studied, much less is known about tetraradicals, as their very low stability has hampered their isolation and use in small-molecul...

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Detalles Bibliográficos
Autores principales: Zander, Edgar, Bresien, Jonas, Zhivonitko, Vladimir V., Fessler, Johannes, Villinger, Alexander, Michalik, Dirk, Schulz, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10368346/
https://www.ncbi.nlm.nih.gov/pubmed/37315222
http://dx.doi.org/10.1021/jacs.3c03928