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C(S)-Symmetric Pyridine(diimine) Iron Methyl Complexes for Catalytic [2+2] Cycloaddition and Hydrovinylation: Metallacycle Geometry Determines Selectivity
[Image: see text] A series of C(S)-symmetric (aryl,alkyl)-substituted pyridine(dimine) iron methyl ((Cy)A(R)PDI)FeCH(3) complexes have been prepared, characterized, and evaluated as precatalysts for the [2+2]-cycloaddition of butadiene and ethylene. Mixtures of vinylcyclobutane and (Z)-hexa-1,4-dien...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10369671/ https://www.ncbi.nlm.nih.gov/pubmed/37502155 http://dx.doi.org/10.1021/jacsau.3c00229 |