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C(S)-Symmetric Pyridine(diimine) Iron Methyl Complexes for Catalytic [2+2] Cycloaddition and Hydrovinylation: Metallacycle Geometry Determines Selectivity

[Image: see text] A series of C(S)-symmetric (aryl,alkyl)-substituted pyridine(dimine) iron methyl ((Cy)A(R)PDI)FeCH(3) complexes have been prepared, characterized, and evaluated as precatalysts for the [2+2]-cycloaddition of butadiene and ethylene. Mixtures of vinylcyclobutane and (Z)-hexa-1,4-dien...

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Detalles Bibliográficos
Autores principales:	Duchemin, Coralie, Kim, Junho, Chirik, Paul J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10369671/ https://www.ncbi.nlm.nih.gov/pubmed/37502155 http://dx.doi.org/10.1021/jacsau.3c00229

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