Terminal methylene phosphonium ions: precursors for transient monosubstituted phosphinocarbenes

Isolable singlet carbenes are among the most important tools in chemistry, but generally require the interaction of two substituents with the electron deficient carbon atom. We herein report a synthetic approach to monosubstituted phosphinocarbenes via deprotonation of hitherto unknown diprotic term...

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Detalles Bibliográficos
Autores principales: Löwe, Pawel, Wünsche, Marius A., Purtscher, Felix R. S., Gamper, Jakob, Hofer, Thomas S., Wilm, Lukas F. B., Röthel, Maike B., Dielmann, Fabian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10370551/
https://www.ncbi.nlm.nih.gov/pubmed/37502319
http://dx.doi.org/10.1039/d3sc02899b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10370551/
https://www.ncbi.nlm.nih.gov/pubmed/37502319
http://dx.doi.org/10.1039/d3sc02899b

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