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Terminal methylene phosphonium ions: precursors for transient monosubstituted phosphinocarbenes
Isolable singlet carbenes are among the most important tools in chemistry, but generally require the interaction of two substituents with the electron deficient carbon atom. We herein report a synthetic approach to monosubstituted phosphinocarbenes via deprotonation of hitherto unknown diprotic term...
Autores principales: | Löwe, Pawel, Wünsche, Marius A., Purtscher, Felix R. S., Gamper, Jakob, Hofer, Thomas S., Wilm, Lukas F. B., Röthel, Maike B., Dielmann, Fabian |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10370551/ https://www.ncbi.nlm.nih.gov/pubmed/37502319 http://dx.doi.org/10.1039/d3sc02899b |
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