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Rhodium-catalyzed atroposelective access to trisubstituted olefins via C–H bond olefination of diverse arenes

The atroposelective synthesis of axially chiral acyclic olefins remains a daunting challenge due to their relatively lower racemization barriers, especially for trisubstituted ones. In this work, atroposelective C–H olefination has been realized for synthesis of open-chain trisubstituted olefins via...

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Detalles Bibliográficos
Autores principales: Zhu, Xiaohan, Mi, Ruijie, Yin, Jie, Wang, Fen, Li, Xingwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10370552/
https://www.ncbi.nlm.nih.gov/pubmed/37502336
http://dx.doi.org/10.1039/d3sc02714g