Helical fused 1,2:8,9-dibenzozethrene oligomers with up to 201° end-to-end twist: “one-pot” synthesis and chiral resolution

Twisted polyarenes with persistent chirality are desirable but their synthesis has remained a challenge. In this study, we present a “one-pot” synthesis of 1,2:8,9-dibenzozethrene (DBZ) and its vertically fused dimers and trimers using nickel-catalyzed cyclo-oligomerization reactions. X-ray crystall...

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Detalles Bibliográficos
Autores principales: Sun, Zhitao, Fan, Wei, Han, Yi, Yuan, Wei, Ni, Yong, Wang, Jinyi, Wei, Haipeng, Zhao, Yanli, Sun, Zhe, Wu, Jishan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10370577/
https://www.ncbi.nlm.nih.gov/pubmed/37502331
http://dx.doi.org/10.1039/d3sc02285d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10370577/
https://www.ncbi.nlm.nih.gov/pubmed/37502331
http://dx.doi.org/10.1039/d3sc02285d

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