Catalytic asymmetric indolization by a desymmetrizing [3 + 2] annulation strategy

A new catalytic asymmetric indolization reaction by a desymmetrizing [3 + 2] annulation strategy is developed. The reaction proceeds via a rhodium-catalyzed enantioposition-selective addition/5-exo-trig cyclization/dehydration cascade between ortho-amino arylboronic acids and 2,2-disubstituted cyclo...

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Detalles Bibliográficos
Autores principales: Wu, Changhui, Chang, Zhiqian, Peng, Chuanyong, Bai, Chen, Xing, Junhao, Dou, Xiaowei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10370590/
https://www.ncbi.nlm.nih.gov/pubmed/37502333
http://dx.doi.org/10.1039/d3sc02474a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10370590/
https://www.ncbi.nlm.nih.gov/pubmed/37502333
http://dx.doi.org/10.1039/d3sc02474a

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