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Precise cooperative sulfur placement leads to semi-crystallinity and selective depolymerisability in CS(2)/oxetane copolymers

CS(2) promises easy access to degradable sulfur-rich polymers and insights into how main-group derivatisation affects polymer formation and properties, though its ring-opening copolymerisation is plagued by low linkage selectivity and small-molecule by-products. We demonstrate that a cooperative Cr(...

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Detalles Bibliográficos
Autores principales: Fornacon-Wood, Christoph, Manjunatha, Bhargav R., Stühler, Merlin R., Gallizioli, Cesare, Müller, Carsten, Pröhm, Patrick, Plajer, Alex J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10374558/
https://www.ncbi.nlm.nih.gov/pubmed/37500621
http://dx.doi.org/10.1038/s41467-023-39951-y