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Precise cooperative sulfur placement leads to semi-crystallinity and selective depolymerisability in CS(2)/oxetane copolymers
CS(2) promises easy access to degradable sulfur-rich polymers and insights into how main-group derivatisation affects polymer formation and properties, though its ring-opening copolymerisation is plagued by low linkage selectivity and small-molecule by-products. We demonstrate that a cooperative Cr(...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10374558/ https://www.ncbi.nlm.nih.gov/pubmed/37500621 http://dx.doi.org/10.1038/s41467-023-39951-y |