Cargando…
Force-Triggered Atropisomerization of a Parallel Diarylethene to Its Antiparallel Diastereomers
[Image: see text] This paper describes a mechanical approach to inducing the atropisomerization of a parallel diarylethene into its antiparallel diastereomers exhibiting distinct chemical reactivity. A congested parallel diarylethene mechanophore in the (R(a),S(a))-configuration with mirror symmetry...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10375474/ https://www.ncbi.nlm.nih.gov/pubmed/37413689 http://dx.doi.org/10.1021/jacs.3c03994 |