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Structural and energetic insights into Mn-to-Fe substitution in the oxygen-evolving complex

Manganese (Mn) serves as the catalytic center for water splitting in photosystem II (PSII), despite the abundance of iron (Fe) on earth. As a first step toward why Mn and not Fe is employed by Nature in the water oxidation catalyst, we investigated the Fe(4)CaO(5) cluster in the PSII protein environ...

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Detalles Bibliográficos
Autores principales: Saito, Masahiro, Saito, Keisuke, Ishikita, Hiroshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10382916/
https://www.ncbi.nlm.nih.gov/pubmed/37520740
http://dx.doi.org/10.1016/j.isci.2023.107352