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Structural and energetic insights into Mn-to-Fe substitution in the oxygen-evolving complex
Manganese (Mn) serves as the catalytic center for water splitting in photosystem II (PSII), despite the abundance of iron (Fe) on earth. As a first step toward why Mn and not Fe is employed by Nature in the water oxidation catalyst, we investigated the Fe(4)CaO(5) cluster in the PSII protein environ...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10382916/ https://www.ncbi.nlm.nih.gov/pubmed/37520740 http://dx.doi.org/10.1016/j.isci.2023.107352 |