Unanticipated switch of reactivity of isonitrile via N≡C bond scission: Cascade formation of symmetrical sulfonyl guanidine

Unanticipated formation of symmetrical sulfonyl guanidine was observed while treating isonitriles with N,N-dibromoarylsulfonamides in absence of an external amine source. Interesting feature of this work is that one molecule of isonitrile initially reacts with dibromoarylsulfonamide via the C-end to...

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Detalles Bibliográficos
Autores principales: Mishra, Debashish, Rajkhowa, Sagarika, Phukan, Prodeep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10384224/
https://www.ncbi.nlm.nih.gov/pubmed/37520733
http://dx.doi.org/10.1016/j.isci.2023.107258

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10384224/
https://www.ncbi.nlm.nih.gov/pubmed/37520733
http://dx.doi.org/10.1016/j.isci.2023.107258

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