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Kinetics of Polycycloaddition of Flexible α-Azide-ω-Alkynes Having Different Spacer Length

Two flexible α-azide-ω-alkynes differing in the length of the hydrocarbon spacers (C(8) vs. C(12)) between functional groups are synthesized. Their bulk polymerization kinetics is studied by differential scanning calorimetry (DSC) and parameterized with the aid of isoconversional methodology. The mo...

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Detalles Bibliográficos
Autores principales: Galukhin, Andrey, Aleshin, Roman, Nosov, Roman, Vyazovkin, Sergey
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10385033/
https://www.ncbi.nlm.nih.gov/pubmed/37514496
http://dx.doi.org/10.3390/polym15143109