Ge–Cu-Complexes Ph(pyO)Ge(μ(2)-pyO)(2)CuCl and PhGe(μ(2)-pyO)(4)CuCl—Representatives of Cu(I)→Ge(IV) and Cu(II)→Ge(IV) Dative Bond Systems

Phenylgermaniumpyridine-2-olate PhGe(pyO)(3) (compound 1Ge) and CuCl react with the formation of the heteronuclear complex Ph(pyO)Ge(μ(2)-pyO)(2)CuCl (2Ge’) rather than forming the expected compound PhGe(μ(2)-pyO)(3)CuCl (2Ge). Single-point calculations (at the B2T-PLYP level) of the optimized molec...

Descripción completa

Detalles Bibliográficos
Autores principales: Wagler, Jörg, Gericke, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10385301/
https://www.ncbi.nlm.nih.gov/pubmed/37513314
http://dx.doi.org/10.3390/molecules28145442

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10385301/
https://www.ncbi.nlm.nih.gov/pubmed/37513314
http://dx.doi.org/10.3390/molecules28145442

Ejemplares similares