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Ge–Cu-Complexes Ph(pyO)Ge(μ(2)-pyO)(2)CuCl and PhGe(μ(2)-pyO)(4)CuCl—Representatives of Cu(I)→Ge(IV) and Cu(II)→Ge(IV) Dative Bond Systems
Phenylgermaniumpyridine-2-olate PhGe(pyO)(3) (compound 1Ge) and CuCl react with the formation of the heteronuclear complex Ph(pyO)Ge(μ(2)-pyO)(2)CuCl (2Ge’) rather than forming the expected compound PhGe(μ(2)-pyO)(3)CuCl (2Ge). Single-point calculations (at the B2T-PLYP level) of the optimized molec...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10385301/ https://www.ncbi.nlm.nih.gov/pubmed/37513314 http://dx.doi.org/10.3390/molecules28145442 |