Divergent Catalysis: Catalytic Asymmetric [4+2] Cycloaddition of Palladium Enolates

[Image: see text] An asymmetric decarboxylative [4+2] cycloaddition from a catalytically generated chiral Pd enolate was developed, forging four contiguous stereocenters in a single transformation. This was achieved through a strategy termed divergent catalysis, wherein departure from a known cataly...

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Detalles Bibliográficos
Autores principales: Flesch, Kaylin N., Cusumano, Alexander Q., Chen, Peng-Jui, Strong, Christian Santiago, Sardini, Stephen R., Du, Yun E., Bartberger, Michael D., Goddard, William A., Stoltz, Brian M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10388310/
https://www.ncbi.nlm.nih.gov/pubmed/37186945
http://dx.doi.org/10.1021/jacs.3c02104

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10388310/
https://www.ncbi.nlm.nih.gov/pubmed/37186945
http://dx.doi.org/10.1021/jacs.3c02104

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