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Revisiting the origin of the bending in group 2 metallocenes AeCp(2) (Ae = Be–Ba)

Metallocenes are well-established compounds in organometallic chemistry, and can exhibit either a coplanar structure or a bent structure according to the nature of the metal center (E) and the cyclopentadienyl ligands (Cp). Herein, we re-examine the chemical bonding to underline the origins of the g...

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Detalles Bibliográficos
Autores principales: Sergeieva, Tetiana, Demirer, T. Ilgin, Wuttke, Axel, Mata, Ricardo A., Schäfer, André, Linker, Gerrit-Jan, Andrada, Diego M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10395002/
https://www.ncbi.nlm.nih.gov/pubmed/37482883
http://dx.doi.org/10.1039/d2cp05020j