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Comparative study of CO(2) insertion into pincer supported palladium alkyl and aryl complexes

The insertion of CO(2) into metal alkyl bonds is a crucial elementary step in transition metal-catalyzed processes for CO(2) utilization. Here, we synthesize pincer-supported palladium complexes of the type ((tBu)PBP)Pd(alkyl) ((tBu)PBP = B(NCH(2)P(t)Bu(2))(2)C(6)H(4)(−); alkyl = CH(2)CH(3), CH(2)CH...

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Detalles Bibliográficos
Autores principales: Deziel, Anthony P., Gahlawat, Sahil, Hazari, Nilay, Hopmann, Kathrin H., Mercado, Brandon Q.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10395277/
https://www.ncbi.nlm.nih.gov/pubmed/37538821
http://dx.doi.org/10.1039/d3sc01459b