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Comparative study of CO(2) insertion into pincer supported palladium alkyl and aryl complexes
The insertion of CO(2) into metal alkyl bonds is a crucial elementary step in transition metal-catalyzed processes for CO(2) utilization. Here, we synthesize pincer-supported palladium complexes of the type ((tBu)PBP)Pd(alkyl) ((tBu)PBP = B(NCH(2)P(t)Bu(2))(2)C(6)H(4)(−); alkyl = CH(2)CH(3), CH(2)CH...
Autores principales: | Deziel, Anthony P., Gahlawat, Sahil, Hazari, Nilay, Hopmann, Kathrin H., Mercado, Brandon Q. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10395277/ https://www.ncbi.nlm.nih.gov/pubmed/37538821 http://dx.doi.org/10.1039/d3sc01459b |
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