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Acetate exchange mechanism on a Zr(12) oxo hydroxo cluster: relevance for reshaping Zr–carboxylate coordination adaptable networks
The kinetics and mechanism of the acetate ligand exchange with free acetic acid in [Zr(6)O(4)(OH)(4)(O(2)CCH(3))(12)](2), used as a molecular model of crosslink migration in [Zr(6)O(4)(OH)(4)(carboxylate)(12−n)(OH)(n)]-based coordination adaptable networks with vitrimer-like properties, has been tho...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10395313/ https://www.ncbi.nlm.nih.gov/pubmed/37538814 http://dx.doi.org/10.1039/d3sc02204h |