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Selective nucleophilic α-C alkylation of phenols with alcohols via Ti=C(α) intermediate on anatase TiO(2) surface
C−C bond forming reaction by alkylation of aryl rings is a main pillar of chemistry in the production of broad portfolios of chemical products. The dominant mechanism proceeds via electrophilic substitution of secondary and tertiary carbocations over acid catalysts, forming multiple aryl alkylation...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10397351/ https://www.ncbi.nlm.nih.gov/pubmed/37532708 http://dx.doi.org/10.1038/s41467-023-40101-7 |