Rhodium-catalyzed enantioselective and diastereodivergent access to diaxially chiral heterocycles

N-N axially chiral biaryls represent a rarely explored class of atropisomers. Reported herein is construction of diverse classes of diaxially chiral biaryls containing N-N and C-N/C-C diaxes in distal positions in excellent enantioselectivity and diastereoselectivity. The N-N chiral axis in the prod...

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Detalles Bibliográficos
Autores principales: Wang, Yishou, Zhu, Xiaohan, Pan, Deng, Jing, Jierui, Wang, Fen, Mi, Ruijie, Huang, Genping, Li, Xingwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10400608/
https://www.ncbi.nlm.nih.gov/pubmed/37537163
http://dx.doi.org/10.1038/s41467-023-39968-3

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10400608/
https://www.ncbi.nlm.nih.gov/pubmed/37537163
http://dx.doi.org/10.1038/s41467-023-39968-3

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