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Enzymatic Hydroxylation of Aliphatic C–H Bonds by a Mn/Fe Cofactor

[Image: see text] The aerobic oxidation of carbon–hydrogen (C–H) bonds in biology is currently known to be accomplished by a limited set of cofactors that typically include heme, nonheme iron, and copper. While manganese cofactors perform difficult oxidation reactions, including water oxidation with...

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Detalles Bibliográficos
Autores principales: Powell, Magan M., Rao, Guodong, Britt, R. David, Rittle, Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10401708/
https://www.ncbi.nlm.nih.gov/pubmed/37471626
http://dx.doi.org/10.1021/jacs.3c03419