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Iridium-Catalyzed Asymmetric Difunctionalization of C–C σ-Bonds Enabled by Ring-Strained Boronate Complexes

[Image: see text] Enantioenriched organoboron intermediates are important building blocks in organic synthesis and drug discovery. Recently, transition metal-catalyzed enantioselective 1,2-metalate rearrangements of alkenylboronates have emerged as an attractive protocol to access these valuable rea...

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Detalles Bibliográficos
Autores principales: Shen, Hong-Cheng, Popescu, Mihai V., Wang, Ze-Shu, de Lescure, Louis, Noble, Adam, Paton, Robert S., Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10401714/
https://www.ncbi.nlm.nih.gov/pubmed/37471704
http://dx.doi.org/10.1021/jacs.3c03248