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Iridium-Catalyzed Asymmetric Difunctionalization of C–C σ-Bonds Enabled by Ring-Strained Boronate Complexes
[Image: see text] Enantioenriched organoboron intermediates are important building blocks in organic synthesis and drug discovery. Recently, transition metal-catalyzed enantioselective 1,2-metalate rearrangements of alkenylboronates have emerged as an attractive protocol to access these valuable rea...
Autores principales: | Shen, Hong-Cheng, Popescu, Mihai V., Wang, Ze-Shu, de Lescure, Louis, Noble, Adam, Paton, Robert S., Aggarwal, Varinder K. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10401714/ https://www.ncbi.nlm.nih.gov/pubmed/37471704 http://dx.doi.org/10.1021/jacs.3c03248 |
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