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Site-selective and metal-free C–H phosphonation of arenes via photoactivation of thianthrenium salts

Aryl phosphonates are prevalent moieties in medicinal chemistry and agrochemicals. Their chemical synthesis normally relies on the use of precious metals, harsh conditions or aryl halides as substrates. Herein, we describe a sustainable light-promoted and site-selective C–H phosphonation of arenes v...

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Detalles Bibliográficos
Autores principales: Gallego-Gamo, Albert, Reyes-Mesa, David, Guinart-Guillem, Axel, Pleixats, Roser, Gimbert-Suriñach, Carolina, Vallribera, Adelina, Granados, Albert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10407877/
https://www.ncbi.nlm.nih.gov/pubmed/37559697
http://dx.doi.org/10.1039/d3ra04512a