Formation of Irida-β-ketoimines and PCN(amine)-Ir(III) Complexes by Reacting Irida-β-diketones with Aliphatic Diamines: Catalytic Activity in Hydrogen Release by Methanolysis of H(3)N–BH(3)

[Image: see text] Aliphatic diamines [(H(2)N(CH(2))(n)NHR) (a–d) n = 2: R = H (a), R = CH(3) (b), R = C(2)H(5) (c), n = 3, R = H (d) or rac-2-(aminomethyl)piperidine (e)] react with [IrH(Cl){(PPh(2)(o-C(6)H(4)CO))(2)H}] in THF to afford ketoimine complexes [IrH(Cl){(PPh(2)(o-C(6)H(4)CO))(PPh(2)(o-C(...

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Detalles Bibliográficos
Autores principales: Bustos, Itxaso, Seco, Jose M., Rodriguez-Dieguez, Antonio, Garralda, María A., Mendicute-Fierro, Claudio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10407880/
https://www.ncbi.nlm.nih.gov/pubmed/37559938
http://dx.doi.org/10.1021/acs.organomet.2c00451

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10407880/
https://www.ncbi.nlm.nih.gov/pubmed/37559938
http://dx.doi.org/10.1021/acs.organomet.2c00451

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