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Lewis Acid-Catalyzed Carbonyl-Ene Reaction: Interplay between Aromaticity, Synchronicity, and Pauli Repulsion
[Image: see text] The physical factors governing the catalysis in Lewis acid-promoted carbonyl-ene reactions have been explored in detail quantum chemically. It is found that the binding of a Lewis acid to the carbonyl group directly involved in the transformation greatly accelerates the reaction by...
Autores principales: | Rodríguez, Humberto A., Cruz, Daniel A., Padrón, Juan I., Fernández, Israel |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10407925/ https://www.ncbi.nlm.nih.gov/pubmed/37485981 http://dx.doi.org/10.1021/acs.joc.3c01059 |
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