Bimetallic tandem catalysis-enabled enantioselective cycloisomerization/carbonyl–ene reaction for construction of 5-oxazoylmethyl α-silyl alcohol

A bimetallic tandem catalysis-enabled enantioselective cycloisomerization/carbonyl–ene reaction was developed. The reaction proceeded well with a broad range of N-propargylamides and acylsilanes, affording the target chiral 5-oxazoylmethyl α-silyl alcohols in up to 95% yield and 99% ee under mild co...

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Detalles Bibliográficos
Autores principales: Sang, Xinpeng, Mo, Yuhao, Li, Shiya, Liu, Xiaohua, Cao, Weidi, Feng, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10411629/
https://www.ncbi.nlm.nih.gov/pubmed/37564412
http://dx.doi.org/10.1039/d3sc01048a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10411629/
https://www.ncbi.nlm.nih.gov/pubmed/37564412
http://dx.doi.org/10.1039/d3sc01048a

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