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[Cs©C(18)](+) and [Na©C(14)](+): perfect planar alkaline-metal-centered polyynic cyclo[n]carbon complexes with record coordination numbers

Searching for the maximum coordination number (CN) in planar species with novel bonding patterns has fascinated chemists for many years. Using the experimentally observed polyynic cyclo[18]carbon D(9h) C(18) and theoretically predicted polyynic cyclo[14]carbon D(7h) C(14) as effective ligands and ba...

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Detalles Bibliográficos
Autores principales: Zhang, Min, Yuan, Rui-Nan, Wu, Yan-Bo, Chen, Qiang, Wei, Zhihong, Li, Si-Dian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10413334/
https://www.ncbi.nlm.nih.gov/pubmed/37577084
http://dx.doi.org/10.1039/d3ra03930g