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A computational study on the coordination modes and electron absorption spectra of the complexes U(iv) with N,N,N′,N′-tetramethyl-diglycolamide and anions

Lipophilic N,N,N′,N′-tetraalkyl-diglycolamides (TRDGAs) are promising extractants for actinides separation in spent nuclear fuel reprocessing. Usually, in the extracted complexes of actinide and lanthanide ions of various oxidation states, the metal ions are completely surrounded by 2 or 3 TRDGA mol...

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Detalles Bibliográficos
Autores principales: Yang, Yating, Lan, Youshi, Liu, Qian, Zhu, Liyang, Hao, Xuan, Zhou, Jin, Yang, Suliang, Tian, Guoxin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10413335/
https://www.ncbi.nlm.nih.gov/pubmed/37577087
http://dx.doi.org/10.1039/d3ra04206e