Isolation of Hemiketal and Hydroxy Ketone Tautomers of Synthetic Intermediates Each Affording 18-Hydroxycortisol-1,6,7-d(3)

[Image: see text] During the synthesis of deuterated 18-hydroxycortisol, two of the synthetic intermediates have been found to exist in tautomeric forms as the acyclic 18-hydroxy 20-ketone and the cyclic 18,20-hemiketal corresponding to the previously identified less polar (L) and more polar (M) for...

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Detalles Bibliográficos
Autores principales: Lewin, Anita H., Hayes, James P., Zhong, Desong, Zhang, Dehui, Kormos, Chad M., Mascarella, S. Wayne, Seltzman, Herbert. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10413467/
https://www.ncbi.nlm.nih.gov/pubmed/37576635
http://dx.doi.org/10.1021/acsomega.3c01648

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10413467/
https://www.ncbi.nlm.nih.gov/pubmed/37576635
http://dx.doi.org/10.1021/acsomega.3c01648

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