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Reduction of K(+) or Li(+) in the Heterobimetallic Electride K(+)[LiN(SiMe(3))(2)]e(–)
[Image: see text] Given their very negative redox potential (e.g., Li(+) → Li(0), −3.04 V; K(+) → K(0), −2.93 V), chemical reduction of Group-1 metal cations is one of the biggest challenges in inorganic chemistry: they are widely accepted as irreducible in the synthetic chemistry regime. Their redu...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10416298/ https://www.ncbi.nlm.nih.gov/pubmed/37478322 http://dx.doi.org/10.1021/jacs.3c06066 |