Photochemical Uncaging of Aldehydes and Ketones via Photocyclization/Fragmentation Cascades of Enyne Alcohols: An Unusual Application for a Cycloaromatization Process

We utilized a cycloaromatization reaction driven by relief of excited state antiaromaticity to photouncage aldehydes and ketones. We developed several synthetic routes towards the synthesis of photocaged carbonyls as allylically substituted 3-(2-(arylethynyl)phenyl)prop-2-en-1-ols. A library of phot...

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Detalles Bibliográficos
Autores principales: Campbell, Adam, Dos Santos, Nikolas R., Alabugin, Igor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10420836/
https://www.ncbi.nlm.nih.gov/pubmed/37570675
http://dx.doi.org/10.3390/molecules28155704

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10420836/
https://www.ncbi.nlm.nih.gov/pubmed/37570675
http://dx.doi.org/10.3390/molecules28155704

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