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From K(6)[Re(6−x)Mo(x)S(8)(CN)(5)] Solid Solution to Individual Cluster Complexes: Separation and Investigation of [Re(4)Mo(2)S(8)(CN)(6)](n−) and [Re(3)Mo(3)S(8)(CN)(6)](n−) Heterometallic Clusters

A series of new cluster compounds with {Re(4)Mo(2)S(8)} and {Re(3)Mo(3)S(8)} cores has been obtained and investigated. The clusters with different Re/Mo ratios were isolated as individual compounds, which made it possible to study their spectroscopic and electrochemical properties. The geometry of t...

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Detalles Bibliográficos
Autores principales: Lappi, Tatiana I., Gayfulin, Yakov M., Renaud, Adèle, Prestipino, Carmelo, Lemoine, Pierric, Yanshole, Vadim V., Muravieva, Viktoria K., Cordier, Stéphane, Naumov, Nikolai G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10421489/
https://www.ncbi.nlm.nih.gov/pubmed/37570845
http://dx.doi.org/10.3390/molecules28155875