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Intramolecular cyclization of N-cyano sulfoximines by N–CN bond activation

Metal-free halogenated anhydrides promote the intramolecular cyclization of N-cyano sulfoximines. Trifluoro- or trichloroacetic anhydride (TFAA or TCAA, respectively) activate the N-cyano groups of N-cyano sulfoximines, leading to the intramolecular cyclization of 2-benzamide-N-cyano sulfoximines 1....

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Detalles Bibliográficos
Autores principales: Seo, Ye Ji, Kim, Eunsil, Oh, In Seok, Hyun, Ji Young, Song, Ji Ho, Lim, Hwan Jung, Park, Seong Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10424563/
https://www.ncbi.nlm.nih.gov/pubmed/37583669
http://dx.doi.org/10.1039/d3ra04208a