Enantioconvergent construction of stereogenic silicon via Lewis base-catalyzed dynamic kinetic silyletherification of racemic chlorosilanes

Organosilanes possessing an enantioenriched stereogenic silicon center are important in many branches of chemistry, yet they remain challenging to synthesize in a practical and scalable way. Here we report a dynamic kinetic silyletherification process of racemic chlorosilanes with (S)-lactates using...

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Detalles Bibliográficos
Autores principales: Hu, Tianbao, Zhao, Chen, Zhang, Yan, Kuang, Yuzhong, Gao, Lu, Wang, Wanshu, Su, Zhishan, Song, Zhenlei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10425371/
https://www.ncbi.nlm.nih.gov/pubmed/37580365
http://dx.doi.org/10.1038/s41467-023-40558-6

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10425371/
https://www.ncbi.nlm.nih.gov/pubmed/37580365
http://dx.doi.org/10.1038/s41467-023-40558-6

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