Symmetry Breaking and Cooperative Spin Crossover in a Hofmann-Type Coordination Polymer Based on Negatively Charged {Fe(II)(μ(2)-[M(II)(CN)(4)])(2)}(n)(2n–) Layers (M(II) = Pd, Pt)

[Image: see text] We report herein the synthesis and characterization of two unprecedented isomorphous spin-crossover two-dimensional coordination polymers of the Hofmann-type formulated {Fe(II)(Hdpyan)(2)(μ(2)-[M(II)(CN)(4)])(2)}, with M(II) = Pd, Pt and Hdpyan is the in situ partially protonated f...

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Detalles Bibliográficos
Autores principales: Orellana-Silla, Alejandro, Meneses-Sánchez, Manuel, Turo-Cortés, Rubén, Muñoz, M. Carmen, Bartual-Murgui, Carlos, Real, José Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10428219/
https://www.ncbi.nlm.nih.gov/pubmed/37526289
http://dx.doi.org/10.1021/acs.inorgchem.3c01332

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10428219/
https://www.ncbi.nlm.nih.gov/pubmed/37526289
http://dx.doi.org/10.1021/acs.inorgchem.3c01332

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