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Symmetry Breaking and Cooperative Spin Crossover in a Hofmann-Type Coordination Polymer Based on Negatively Charged {Fe(II)(μ(2)-[M(II)(CN)(4)])(2)}(n)(2n–) Layers (M(II) = Pd, Pt)
[Image: see text] We report herein the synthesis and characterization of two unprecedented isomorphous spin-crossover two-dimensional coordination polymers of the Hofmann-type formulated {Fe(II)(Hdpyan)(2)(μ(2)-[M(II)(CN)(4)])(2)}, with M(II) = Pd, Pt and Hdpyan is the in situ partially protonated f...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10428219/ https://www.ncbi.nlm.nih.gov/pubmed/37526289 http://dx.doi.org/10.1021/acs.inorgchem.3c01332 |