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Luminescent Au(III)–M(I) (M = Cu, Ag) Aggregates Based on Dicyclometalated Bis(alkynyl) Gold Anions†

[Image: see text] The syntheses and structures of a series of complexes based on the C(∧)C-chelated Au(III) unit (C(∧)C = 4,4′-bis(t-butyl) 2,2′-biphenyl-1,1′-diyl) are reported, namely, [{(C(∧)C)Au(C≡C(t)Bu)(2)}(2)M(2)], (C(∧)C)Au(C≡CR)(C≡NXyl), and [{(C(∧)C)Au(C≡CR)(2)}{M(C≡NXyl)}] (M = Ag, Cu; R...

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Detalles Bibliográficos
Autores principales: Lara Garnica, Rebeca, Rama, Raquel J., Chambrier, Isabelle, Agonigi, Gabriele, Hughes, David L., Lalinde, Elena, Bochmann, Manfred, Fernandez-Cestau, Julio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10428224/
https://www.ncbi.nlm.nih.gov/pubmed/37534700
http://dx.doi.org/10.1021/acs.inorgchem.3c00870