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Luminescent Au(III)–M(I) (M = Cu, Ag) Aggregates Based on Dicyclometalated Bis(alkynyl) Gold Anions†
[Image: see text] The syntheses and structures of a series of complexes based on the C(∧)C-chelated Au(III) unit (C(∧)C = 4,4′-bis(t-butyl) 2,2′-biphenyl-1,1′-diyl) are reported, namely, [{(C(∧)C)Au(C≡C(t)Bu)(2)}(2)M(2)], (C(∧)C)Au(C≡CR)(C≡NXyl), and [{(C(∧)C)Au(C≡CR)(2)}{M(C≡NXyl)}] (M = Ag, Cu; R...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10428224/ https://www.ncbi.nlm.nih.gov/pubmed/37534700 http://dx.doi.org/10.1021/acs.inorgchem.3c00870 |